Publications: 2015 – 2019 2015 | 2016 | 2017 | 2018 | 2019 2019 Physical methods for mechanistic understanding: general discussion Understanding unusual element-element bond formation and activation: general discussion Insight into the mechanism of CO-release from trypto-CORM using ultra-fast spectroscopy and computational chemistry A biotin-conjugated photo-activated CO-releasing molecule (biotinCORM): efficient CO-release from an avidin–biotinCORM protein adduct The ubiquitous cross-coupling catalyst system ‘Pd(OAc)2’/2PPh3 forms a unique dinuclear PdI complex: an important entry point into catalytically competent cyclic Pd2 clusters Chapter9 – Palladacycles as Potential Anticancer AgentsChapter9 – Palladacycles as Potential Anticancer Agents Manganese Carbonyl Compounds Reveal Ultrafast Metal–Solvent Interactions Solvent effects in palladium catalysed cross-coupling reactions Delineating the critical role of acid additives in Mn-catalysed C–H bond functionalisation processes Mechanistic Insight into Catalytic Redox-Neutral C–H Bond Activation Involving MnI Carbonyls: Catalyst Activation, Turnover, and Deactivation Pathways Reveal an Intricate Network of Steps The critical role played by water in controlling Pd catalyst speciation in arylcyanation reactions 2018 Carbon Monoxide-Releasing Molecules: Design Principles Inspired by Mechanism, Enabling Activity to be Controlled and Tuned Mapping out the key carbon–carbon bond-forming steps in Mn-catalysed C–H functionalization Heteroatom Donor-Decorated Polymer-Immobilized Ionic Liquid Stabilized Palladium Nanoparticles: Efficient Catalysts for Room-Temperature Suzuki-Miyaura Cross-Coupling in Aqueous Media The Broad Aryl Acid Specificity of the Amide Bond Synthetase McbA Suggests Potential for the Biocatalytic Synthesis of Amides The Antimicrobial Activity of a Carbon Monoxide Releasing Molecule (EBOR-CORM-1) Is Shaped by Intraspecific Variation within Pseudomonas aeruginosa Populations Transition-Metal Catalyzed Modification of Nucleosides 2017 Access to Some C5-Cyclised 2-Pyrones and 2-Pyridones via Direct Arylation; Retention of Chloride as a Synthetic Handle Mild and Regioselective Pd(OAc)2-Catalyzed C–H Arylation of Tryptophans by [ArN2]X, Promoted by Tosic Acid Redox-Tagged Carbon Monoxide-Releasing Molecules (CORMs): Ferrocene-Containing [Mn(C^N)(CO)4] Complexes as a Promising New CORM Class Highly efficient aqueous phase chemoselective hydrogenation of α,β-unsaturated aldehydes catalysed by phosphine-decorated polymer immobilized IL-stabilized PdNPs Redox Couple Involving NOx in Aerobic Pd-Catalyzed Oxidation of sp3-C–H Bonds: Direct Evidence for Pd–NO3–/NO2– Interactions Involved in Oxidation and Reductive Elimination Chapter 2 – Directed C-H Bond Functionalization Strategies for SynthesisChapter9 – Palladacycles as Potential Anticancer Agents Toxicity of tryptophan MnI carbonyl (Trypto-CORM), against Neisseria gonorrhoeae 2016 Photoactivated Functionizable Tetracarbonyl(phenylpyridine)MnI Complexes as CO-Releasing Molecules: A Direct Suzuki–Miyaura Cross-Coupling on a Thermally Stable CO-RM MnI-Catalyzed C−H Activation: The Key Role of a 7-Membered Manganacycle in H-Transfer and Reductive Elimination Catalyst Efficacy of Homogeneous and Heterogeneous Palladium Catalysts in the Direct Arylation of Common Heterocycles Pd-catalysed Cross-couplings for the Pharmaceutical Sector and a Move to Cutting-edge C–H Bond Functionalization: Is Palladium Simply Too Precious? Theoretical rationalisation for the mechanism of N-heterocyclic carbene-halide reductive elimination at CuIII, AgIII and AuIII Palladium-Catalyzed Synthesis of Macrocycles 2015 Total Synthesis and Stereochemical Revision of Phacelocarpus 2-Pyrone A Investigating pyridazine and phthalazine exchange in a series of iridium complexes in order to define their role in the catalytic transfer of magnetisation from para-hydrogen Catalytic C–H bond functionalisation chemistry: the case for quasi-heterogeneous catalysis The Role of Fluorine Substituents in the Regioselectivity of Intramolecular C–H Bond Functionalization of Benzylamines at PdII Redox-Active NOx Ligands in Palladium-Mediated Processes Unified mild reaction conditions for C2-selective Pd-catalysed tryptophan arylation, including tryptophan-containing peptides Catalytic C–H bond functionalisation of purine and pyrimidine nucleosides: a synthetic and mechanistic perspective Mechanistic Elucidation of the Arylation of Non-Spectator N-Heterocyclic Carbenes at Copper Using a Combined Experimental and Computational Approach Lead-oriented synthesis: Investigation of organolithium-mediated routes to 3-D scaffolds and 3-D shape analysis of a virtual lead-like library Macrocyclic polyenynes: a stereoselective route to vinyl-ether-containing skipped diene systems AsCat and FurCat: new Pd catalysts for selective room-temperature Stille cross-couplings of benzyl chlorides with organostannanes Palladium-catalysed macrocyclisations in the total synthesis of natural products Design and synthesis of fluorescent 7-deazaadenosine nucleosides containing π-extended diarylacetylene motifs Confocal and fluorescence lifetime imaging sheds light on the fate of a pyrene-tagged carbon monoxide-releasing Fischer carbene chromium complex Share this:TwitterFacebookLike Loading...